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Are Brønsted Acids the True Promoter of Metal-Triflate-Catalyzed Glycosylations? A Mechanistic Probe into 1,2-cis-Aminoglycoside Formation by Nickel Triflate

Metal triflates have been utilized to catalytically facilitate numerous glycosylation reactions under mild conditions. In some methods, the metal triflate system provides stereocontrol during the glycosylation, rather than the nature of protecting groups on the substrate. Despite these advances, the...

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Publicat a:ACS Catal
Autors principals: Sletten, Eric T., Tu, Yi-Jung, Schlegel, H. Bernhard, Nguyen, Hien M.
Format: Artigo
Idioma:Inglês
Publicat: 2019
Matèries:
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC6900934/
https://ncbi.nlm.nih.gov/pubmed/31819822
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acscatal.8b04444
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