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Photochemical Asymmetric Nickel‐Catalyzed Acyl Cross‐Coupling

Photochemical enantioselective nickel‐catalyzed cross‐coupling reactions are difficult to implement. We report a visible‐light‐mediated strategy that successfully couples symmetrical anhydrides and 4‐alkyl dihydropyridines (DHPs) to afford enantioenriched α‐substituted ketones under mild conditions....

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Detalhes bibliográficos
Publicado no:Angew Chem Int Ed Engl
Main Authors: Gandolfo, Eugenio, Tang, Xinjun, Raha Roy, Sudipta, Melchiorre, Paolo
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2019
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6900114/
https://ncbi.nlm.nih.gov/pubmed/31532568
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201910168
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