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A Novel Metastable Pentavalent Plutonium Solid Phase on the Pathway from Aqueous Plutonium(VI) to PuO(2) Nanoparticles
Here we provide evidence that the formation of PuO(2) nanoparticles from oxidized Pu(VI) under alkaline conditions proceeds through the formation of an intermediate Pu(V) solid phase, similar to NH(4)PuO(2)CO(3), which is stable over a period of several months. For the first time, state‐of‐the‐art e...
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Publicado no: | Angew Chem Int Ed Engl |
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Main Authors: | , , , , , , , , , , , , , |
Formato: | Artigo |
Idioma: | Inglês |
Publicado em: |
John Wiley and Sons Inc.
2019
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Assuntos: | |
Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6900038/ https://ncbi.nlm.nih.gov/pubmed/31621992 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201911637 |
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