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Valence self-regulation of sulfur in nanoclusters

The valence self-regulation of sulfur from the “−2” valence state in thiols to the “−1” valence state in hydroxylated thiolates has been accomplished using the Pt(1)Ag(28) nanocluster as a platform—the first time that the “−1” valent sulfur has been detected as S(−1). Two previously unknown nanoclus...

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Publicat a:Sci Adv
Autors principals: Kang, Xi, Xu, Fengqing, Wei, Xiao, Wang, Shuxin, Zhu, Manzhou
Format: Artigo
Idioma:Inglês
Publicat: American Association for the Advancement of Science 2019
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Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC6874481/
https://ncbi.nlm.nih.gov/pubmed/31803835
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1126/sciadv.aax7863
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