Room-Temperature Asymmetric Transfer Hydrogenation of Biomass-Derived Levulinic Acid to Optically Pure γ-Valerolactone Using a Ruthenium Catalyst

[Image: see text] This study presents a first report on ruthenium-catalyzed asymmetric transfer hydrogenation (ATH) of levulinic acid (LA) to chiral γ-valerolactone (GVL). ATH of LA has been explored with Noyori’s chiral catalyst (Ru–TsDPEN) in methanol solvent. Efficacy of ATH reaction of LA was in...

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Publicat a:ACS Omega
Autors principals: Shende, Vaishali S., Raut, Amol B., Raghav, Prathamesh, Kelkar, Ashutosh A., Bhanage, Bhalchandra M.
Format: Artigo
Idioma:Inglês
Publicat: American Chemical Society 2019
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC6868911/
https://ncbi.nlm.nih.gov/pubmed/31763574
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acsomega.9b03424
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