Synthesis, Spectroscopy and Electrochemistry in Relation to DFT Computed Energies of Ferrocene- and Ruthenocene-Containing β-Diketonato Iridium(III) Heteroleptic Complexes. Structure of [(2-Pyridylphenyl)(2)Ir(RcCOCHCOCH(3)]

A series of new ferrocene- and ruthenocene-containing iridium(III) heteroleptic complexes of the type [(ppy)(2)Ir(RCOCHCOR′)], with ppy = 2-pyridylphenyl, R = Fc = Fe(II)(η(5)-C(5)H(4))(η(5)-C(5)H(5)) and R′ = CH(3) (1) or Fc (2), as well as R = Rc = Ru(II)(η(5)-C(5)H(4))(η(5)-C(5)H(5)) and R′ = CH(...

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Publicado no:Molecules
Main Authors: Buitendach, Blenerhassitt E., Conradie, Jeanet, Malan, Frederick P., Niemantsverdriet, J. W. (Hans), Swarts, Jannie C.
Formato: Artigo
Idioma:Inglês
Publicado em: MDPI 2019
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Article
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6864483/
https://ncbi.nlm.nih.gov/pubmed/31671705
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3390/molecules24213923
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