Probing the Fluxional Bonding Nature of Rapid Cope rearrangements in Bullvalene C(10)H(10) and Its Analogs C(8)H(8), C(9)H(10), and C(8)BH(9)

Bullvalene C(10)H(10) and its analogs semibullvalene C(8)H(8), barbaralane C(9)H(10), and 9-Borabarbaralane C(8)BH(9) are prototypical fluxional molecules with rapid Cope rearrangements at finite temperatures. Detailed bonding analyses performed in this work reveal the existence of two fluxional π-b...

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Udgivet i:Sci Rep
Main Authors: Ma, Yuan-Yuan, Yan, Miao, Li, Hai-Ru, Wu, Yan-Bo, Tian, Xin-Xin, Lu, Hai-Gang, Li, Si-Dian
Format: Artigo
Sprog:Inglês
Udgivet: Nature Publishing Group UK 2019
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Article
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC6864245/
https://ncbi.nlm.nih.gov/pubmed/31745136
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/s41598-019-53488-5
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