Modifications to the Aryl Group of dppf-Ligated Ni σ‑Aryl Precatalysts: Impact on Speciation and Catalytic Activity in Suzuki−Miyaura Coupling Reactions

There is currently significant interest in the development of efficient nickel precatalysts for cross-coupling. In this work, 14 nickel(II) precatalysts of the form (dppf)Ni(aryl)(X) (dppf = 1,1′-bis(diphenylphosphino)-ferrocene, X = Cl, Br) were synthesized. In particular, both the electronic and s...

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Vydáno v:Organometallics
Hlavní autoři: Beromi, Megan Mohadjer, Banerjee, Gourab, Brudvig, Gary W., Charboneau, David J., Hazari, Nilay, Lant, Hannah M. C., Mercado, Brandon Q.
Médium: Artigo
Jazyk:Inglês
Vydáno: 2018
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On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC6858066/
https://ncbi.nlm.nih.gov/pubmed/31736532
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.organomet.8b00589
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