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Modifications to the Aryl Group of dppf-Ligated Ni σ‑Aryl Precatalysts: Impact on Speciation and Catalytic Activity in Suzuki−Miyaura Coupling Reactions
There is currently significant interest in the development of efficient nickel precatalysts for cross-coupling. In this work, 14 nickel(II) precatalysts of the form (dppf)Ni(aryl)(X) (dppf = 1,1′-bis(diphenylphosphino)-ferrocene, X = Cl, Br) were synthesized. In particular, both the electronic and s...
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| Veröffentlicht in: | Organometallics |
|---|---|
| Hauptverfasser: | , , , , , , |
| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
2018
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6858066/ https://ncbi.nlm.nih.gov/pubmed/31736532 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.organomet.8b00589 |
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