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B−B Cleavage and Ring‐Expansion of a 1,4,2,3‐Diazadiborinine with N‐Heterocyclic Carbenes

A 1,4,2,3‐diazadiborinine derivative was found to form Lewis adducts with strong two‐electron donors such as N‐heterocyclic and cyclic (alkyl)(amino)carbenes. Depending on the donor, some of these Lewis pairs are thermally unstable, converting to sole B,N‐embedded products upon gentle heating. The p...

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Detalhes bibliográficos
Publicado no:Chemistry
Main Authors: Thiess, Torsten, Mellerup, Soren K., Braunschweig, Holger
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2019
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6856839/
https://ncbi.nlm.nih.gov/pubmed/31429506
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201903259
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