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Living β-selective cyclopolymerization using Ru dithiolate catalysts

Cyclopolymerization (CP) of 1,6-heptadiyne derivatives is a powerful method for synthesizing conjugated polyenes containing five- or six-membered rings via α- or β-addition, respectively. Fifteen years of studies on CP have revealed that user-friendly Ru-based catalysts promoted only α-addition; how...

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Bibliographic Details
Published in:Chem Sci
Main Authors: Jung, Kijung, Ahmed, Tonia S., Lee, Jaeho, Sung, Jong-Chan, Keum, Hyeyun, Grubbs, Robert H., Choi, Tae-Lim
Format: Artigo
Language:Inglês
Published: Royal Society of Chemistry 2019
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Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC6855257/
https://ncbi.nlm.nih.gov/pubmed/31762976
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c9sc01326a
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