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Gold(I)-Catalyzed Aromatization: Expeditious Synthesis of Polyfunctionalized Naphthalenes

A gold-catalyzed 6-endo-dig carbocyclization of alkyne with the pendent diazo group is reported. It provides an expeditious approach for the synthesis of multi-functionalized naphthalene derivatives under mild conditions. Mechanistic studies suggest that a vinyl gold carbene is generated as the key...

詳細記述

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書誌詳細
出版年:iScience
主要な著者: Zhang, Cheng, Hong, Kemiao, Dong, Shanliang, Pei, Chao, Zhang, Xiaolu, He, Ciwang, Hu, Wenhao, Xu, Xinfang
フォーマット: Artigo
言語:Inglês
出版事項: Elsevier 2019
主題:
オンライン・アクセス:https://ncbi.nlm.nih.gov/pmc/articles/PMC6849331/
https://ncbi.nlm.nih.gov/pubmed/31710965
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.isci.2019.10.042
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