Redox-neutral ortho-C–H amination of pinacol arylborates via palladium(ii)/norbornene catalysis for aniline synthesis

A palladium(ii)/norbornene cooperative catalysis enabled redox-neutral ortho-C–H amination of pinacol aryl- or heteroarylborates for the synthesis of structurally diverse anilines is reported. This method is scalable, robust (tolerance of air and moisture), phosphine ligand-free, and compatible with...

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Udgivet i:Chem Sci
Main Authors: Chen, Shuqing, Wang, Peng, Cheng, Hong-Gang, Yang, Chihui, Zhou, Qianghui
Format: Artigo
Sprog:Inglês
Udgivet: Royal Society of Chemistry 2019
Fag:
Chemistry
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC6839810/
https://ncbi.nlm.nih.gov/pubmed/31803416
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c9sc02759a
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