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Oxygen atom transfer with organofunctionalized polyoxovanadium clusters: O-atom vacancy formation with tertiary phosphanes and deoxygenation of styrene oxide
We report a rare example of oxygen atom transfer (OAT) from a polyoxometalate cluster to a series of tertiary phosphanes. Addition of PR(3) (PR(3) = PMe(3), PMe(2)Ph, PMePh(2), PPh(3)) to a neutral methoxide-bridged polyoxovanadate-alkoxide (POV-alkoxide) cluster, [V(6)O(7)(OMe)(12)](0), results in...
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| Veröffentlicht in: | Chem Sci |
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| Hauptverfasser: | , , , |
| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
Royal Society of Chemistry
2019
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6837047/ https://ncbi.nlm.nih.gov/pubmed/31853359 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c9sc02882j |
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