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Conceptual similarities between zeolites and artificial enzymes

By using a Diels–Alder (DA) reaction as a base case, we show that a pure silica zeolite acting as an entropy-trapping scaffold can be synthesized with an organic structure directing agent (OSDA) analogue of the transition state (TS) of the DA reaction. A cavity stabilization of the TS is observed wi...

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Bibliografiske detaljer
Udgivet i:Chem Sci
Main Authors: Gallego, Eva M., Paris, Cecilia, Cantín, Ángel, Moliner, Manuel, Corma, Avelino
Format: Artigo
Sprog:Inglês
Udgivet: Royal Society of Chemistry 2019
Fag:
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC6837030/
https://ncbi.nlm.nih.gov/pubmed/31853356
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c9sc02477h
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