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Total Synthesis of the Marine Ladder Polyether Gymnocin B
Herein we report the first total synthesis of marine ladder polyether gymnocin B (1) based on a two-phase strategy. In Phase I, inspired by the proposed biosynthesis, epoxide-opening cascades assemble 10 out of 15 cyclic ether rings making up the molecular core. In the subsequent Phase II, coalescen...
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| Publicado no: | J Am Chem Soc |
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| Main Authors: | , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2019
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6824195/ https://ncbi.nlm.nih.gov/pubmed/31283211 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.9b04696 |
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