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Dearomatization of Electron-Deficient Phenols to ortho-Quinones Enabled by Bidentate Nitrogen-Ligated I(V) Reagents

Ortho-quinones are versatile functional groups found in nature, materials science, and total synthesis. Despite their broad utility, the synthesis of o-quinones remains a significant challenge, and in particular, access to electron-deficient derivatives remains an unsolved problem. Herein, we report...

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Bibliografische gegevens
Gepubliceerd in:Angew Chem Int Ed Engl
Hoofdauteurs: Xiao, Xiao, Greenwood, Nathaniel S., Wengryniuk, Sarah E.
Formaat: Artigo
Taal:Inglês
Gepubliceerd in: 2019
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Online toegang:https://ncbi.nlm.nih.gov/pmc/articles/PMC6814494/
https://ncbi.nlm.nih.gov/pubmed/31430009
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201909868
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