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Generation and Applications of the Hydroxide Trihydrate Anion, [OH(OH(2))(3)](−), Stabilized by a Weakly Coordinating Cation
The reaction of a strongly basic phosphazene (Schwesinger base) with water afforded the corresponding metastable hydroxide trihydrate [OH(OH(2))(3)](−) salt. This is the first hydroxide solvate that is not in contact with a cation and furthermore one of rare known water‐stabilized hydroxide anions....
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| Опубликовано в: : | Angew Chem Int Ed Engl |
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| Главные авторы: | , , , |
| Формат: | Artigo |
| Язык: | Inglês |
| Опубликовано: |
John Wiley and Sons Inc.
2019
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| Предметы: | |
| Online-ссылка: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6790940/ https://ncbi.nlm.nih.gov/pubmed/31373109 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201908589 |
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