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Spin Delocalization in the Radical Cations of Porphyrin Molecular Wires: A New Perspective on EPR Approaches

[Image: see text] The spin delocalization in the radical cations of a series of ethyne-linked oligoporphyrins was investigated using EPR spectroscopy. The room-temperature spectral envelope for these oligomers deviates significantly from the benchmark N(–0.5) trend in line width expected for a compl...

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Pubblicato in:J Phys Chem Lett
Autori principali: Moise, Gabriel, Tejerina, Lara, Rickhaus, Michel, Anderson, Harry L., Timmel, Christiane R.
Natura: Artigo
Lingua:Inglês
Pubblicazione: American Chemical Society 2019
Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC6778911/
https://ncbi.nlm.nih.gov/pubmed/31512868
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.jpclett.9b02262
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