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Harnessing enzyme plasticity for the synthesis of oxygenated sesquiterpenoids
8-Methoxy-γ-humulene, (E)-8-methoxy-β-farnesene, 12-methoxy-β-sesquiphellandrene and 12-methoxyzingiberene can be synthesised in amorphadiene synthase-catalysed reactions from 8- and 12-methoxyfarnesyl diphosphates due to the highly plastic yet tightly controlled carbocationic chemistry of this sesq...
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| Udgivet i: | Beilstein J Org Chem |
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| Main Authors: | , , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
Beilstein-Institut
2019
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6774066/ https://ncbi.nlm.nih.gov/pubmed/31598175 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.15.215 |
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