X‐ray Magnetic Circular Dichroism Spectroscopy Applied to Nitrogenase and Related Models: Experimental Evidence for a Spin‐Coupled Molybdenum(III) Center

Nitrogenase enzymes catalyze the reduction of atmospheric dinitrogen to ammonia utilizing a Mo‐7Fe‐9S‐C active site, the so‐called FeMoco cluster. FeMoco and an analogous small‐molecule (Et(4)N)[(Tp)MoFe(3)S(4)Cl(3)] cubane have both been proposed to contain unusual spin‐coupled Mo(III) sites with a...

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Publicat a:Angew Chem Int Ed Engl
Autors principals: Kowalska, Joanna K., Henthorn, Justin T., Van Stappen, Casey, Trncik, Christian, Einsle, Oliver, Keavney, David, DeBeer, Serena
Format: Artigo
Idioma:Inglês
Publicat: John Wiley and Sons Inc. 2019
Matèries:
Communications
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC6772009/
https://ncbi.nlm.nih.gov/pubmed/31119827
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201901899
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