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Organocatalytic atroposelective construction of axially chiral arylquinones

Atropisomeric biaryl motifs are ubiquitous in chiral catalysts and ligands. Numerous efficient strategies have been developed for the synthesis of axially chiral biaryls. In contrast, the asymmetric construction of o-quinone-aryl atropisomers has yet to be realized. Inspired by the rapid progress of...

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Shranjeno v:
Bibliografske podrobnosti
izdano v:Nat Commun
Main Authors: Zhu, Shuai, Chen, Ye-Hui, Wang, Yong-Bin, Yu, Peiyuan, Li, Shao-Yu, Xiang, Shao-Hua, Wang, Jun-Qi, Xiao, Jian, Tan, Bin
Format: Artigo
Jezik:Inglês
Izdano: Nature Publishing Group UK 2019
Teme:
Online dostop:https://ncbi.nlm.nih.gov/pmc/articles/PMC6753127/
https://ncbi.nlm.nih.gov/pubmed/31537811
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/s41467-019-12269-4
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