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Organocatalytic atroposelective construction of axially chiral arylquinones

Atropisomeric biaryl motifs are ubiquitous in chiral catalysts and ligands. Numerous efficient strategies have been developed for the synthesis of axially chiral biaryls. In contrast, the asymmetric construction of o-quinone-aryl atropisomers has yet to be realized. Inspired by the rapid progress of...

Ausführliche Beschreibung

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Bibliographische Detailangaben
Veröffentlicht in:Nat Commun
Hauptverfasser: Zhu, Shuai, Chen, Ye-Hui, Wang, Yong-Bin, Yu, Peiyuan, Li, Shao-Yu, Xiang, Shao-Hua, Wang, Jun-Qi, Xiao, Jian, Tan, Bin
Format: Artigo
Sprache:Inglês
Veröffentlicht: Nature Publishing Group UK 2019
Schlagworte:
Online Zugang:https://ncbi.nlm.nih.gov/pmc/articles/PMC6753127/
https://ncbi.nlm.nih.gov/pubmed/31537811
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/s41467-019-12269-4
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