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DNA G-Quadruplexes Activate Heme for Robust Catalysis of Carbene Transfer Reactions
[Image: see text] Guanine-rich single-stranded DNAs and RNAs that fold into G-quadruplexes (GQs) are known to complex tightly with Fe(II)-heme and Fe(III)-heme (hemin), ubiquitous cellular cofactors. Heme–GQ (DNA) complexes, known as heme·DNAzymes, are able to utilize hydrogen peroxide as an oxidant...
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| Publicado no: | ACS Omega |
|---|---|
| Main Authors: | , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
American Chemical Society
2019
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| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6751727/ https://ncbi.nlm.nih.gov/pubmed/31552375 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acsomega.9b02305 |
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