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Diastereofacial Selection in Nitrile Oxide Cycloaddition Reactions. The Anti-Directing Effect of an Allylic Oxygen and Some New Results on the Ring Metalation of Isoxazolines. A Synthesis of (±)-Blastmycinone

The extent of diastereoselectivity associated with the reactions of nitrile oxides with alkenes bearing an allylic oxygen substituent has been studied. Reasonable levels of such diastereoselectivity have been found when the tert-butyldimethylsilyl ether derivative of 3-buten-2-ol (5) or (+)-(S)-isop...

詳細記述

保存先:
書誌詳細
出版年:J Org Chem
主要な著者: Kozikowski, Alan P., Ghosh, Arun K.
フォーマット: Artigo
言語:Inglês
出版事項: 1984
主題:
オンライン・アクセス:https://ncbi.nlm.nih.gov/pmc/articles/PMC6746325/
https://ncbi.nlm.nih.gov/pubmed/31527928
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo00189a024
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