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Enthalpy of Formation of Phosphorus Pentachloride; Derivation of the Enthalpy of Formation of Aqueous Orthophosphoric Acid

When chlorine (real gas, 980 mmHg) combines with white (α) phosphorus to form phosphorus pentachloride at 24.89 °C, 3986.3 ± 2.7 J of heat are liberated per gram of stoichiometrically equivalent Mg(2)P(2)O(7). This value was determined by a dead-ended flow system in an electrically calibrated isoper...

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Detalhes bibliográficos
Publicado no:J Res Natl Bur Stand A Phys Chem
Main Authors: Schumm, R. H., Prosen, E. J., Wagman, D. D.
Formato: Artigo
Idioma:Inglês
Publicado em: National Institute of Standards and Technology 1974
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Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6742818/
https://ncbi.nlm.nih.gov/pubmed/32189788
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.6028/jres.078A.021
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