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Chiral Inversion of Thiolate-Protected Gold Nanoclusters via Core Reconstruction without Breaking a Au–S Bond
[Image: see text] On the basis of density functional theory computations of the well-known chiral Au(38)(SR)(24) nanocluster and its Pd- and Ag-doped derivatives, we propose here a mechanism for chiral inversion that does not require the breaking of a metal–sulfur bond at the metal–ligand interface...
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| Published in: | J Am Chem Soc |
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| Main Authors: | , |
| Format: | Artigo |
| Language: | Inglês |
| Published: |
American Chemical
Society
2019
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| Online Access: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6727375/ https://ncbi.nlm.nih.gov/pubmed/30889350 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.9b01204 |
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