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Synthesis of benzo[d]imidazo[2,1-b]benzoselenoazoles: Cs(2)CO(3)-mediated cyclization of 1-(2-bromoaryl)benzimidazoles with selenium

The synthesis of benzimidazo[2,1-b]benzoselenoazoles is described. The novel ring-closure reaction of 1-(2-bromoaryl)benzimidazoles with Se powder is promoted by Cs(2)CO(3) (2 equiv) in DMF at 150 °C. Moreover, the obtained tetracyclic heterocycles are all novel compounds. Single-crystal X-ray analy...

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Bibliografske podrobnosti
izdano v:Beilstein J Org Chem
Main Authors: Matsumura, Mio, Kitamura, Yuki, Yamauchi, Arisa, Kanazawa, Yoshitaka, Murata, Yuki, Hyodo, Tadashi, Yamaguchi, Kentaro, Yasuike, Shuji
Format: Artigo
Jezik:Inglês
Izdano: Beilstein-Institut 2019
Teme:
Online dostop:https://ncbi.nlm.nih.gov/pmc/articles/PMC6720659/
https://ncbi.nlm.nih.gov/pubmed/31501670
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.15.199
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