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α-Photooxygenation of chiral aldehydes with singlet oxygen

Organocatalytic α-oxygenation of chiral aldehydes with photochemically generated singlet oxygen allows synthesizing chiral 3-substituted 1,2-diols. Stereochemical results indicate that the reaction in the presence of diarylprolinol silyl ethers is highly diastereoselective and that the configuration...

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Detalhes bibliográficos
Publicado no:Beilstein J Org Chem
Main Authors: Walaszek, Dominika J, Jawiczuk, Magdalena, Durka, Jakub, Drapała, Olga, Gryko, Dorota
Formato: Artigo
Idioma:Inglês
Publicado em: Beilstein-Institut 2019
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6720656/
https://ncbi.nlm.nih.gov/pubmed/31501676
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.15.205
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