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Dilute Solution Theory of Polymer Crystal Growth: Fractionation Effects

A nonequilibrium (kinetic) theory of polymer molecular weight (MW) fractionation is formulated and applied to binary and multicomponent polyethylenes crystallized from unstirred xylene solutions. High MW components crystallize more readily than do low MW components. This fractionation effect is enha...

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Dades bibliogràfiques
Publicat a:J Res Natl Bur Stand A Phys Chem
Autors principals: Sanchez, Isaac C., DiMarzio, Edmund A.
Format: Artigo
Idioma:Inglês
Publicat: National Institute of Standards and Technology 1972
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Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC6706571/
https://ncbi.nlm.nih.gov/pubmed/34565859
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.6028/jres.076A.026
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