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Copper-catalyzed dehydrogenative γ-C(sp(3))-H amination of saturated ketones for synthesis of polysubstituted anilines
Metal-catalyzed β-C-H functionalization of saturated carbonyls via dehydrogenative desaturation proved to be a powerful tool for simplifying synthesis of valuable β-substituted carbonyls. Here, we report a copper-catalyzed dehydrogenative γ-C(sp(3))-H amination of saturated ketones that initiates th...
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| Publié dans: | Nat Commun |
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| Auteurs principaux: | , , , , |
| Format: | Artigo |
| Langue: | Inglês |
| Publié: |
Nature Publishing Group UK
2019
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| Sujets: | |
| Accès en ligne: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6695438/ https://ncbi.nlm.nih.gov/pubmed/31417081 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/s41467-019-11624-9 |
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