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Synthesis of a [6]rotaxane with singly threaded γ-cyclodextrins as a single stereoisomer

A series of hetero [4]-, [5]- and [6]rotaxanes containing both cucurbit[6]uril (CB[6]) and γ-cyclodextrin (γ-CD) as the macrocyclic components have been synthesized via a threading-followed-by-stoppering approach. Due to the orthogonal binding of CB[6] to ammonium and γ-CD to biphenylene/tetra(ethyl...

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Detalhes bibliográficos
Publicado no:Beilstein J Org Chem
Main Authors: Man, Jason Yin Hei, Au-Yeung, Ho Yu
Formato: Artigo
Idioma:Inglês
Publicado em: Beilstein-Institut 2019
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6693375/
https://ncbi.nlm.nih.gov/pubmed/31467603
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.15.177
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