Redox Cofactor Rotates during Its Stepwise Decarboxylation: Molecular Mechanism of Conversion of Coproheme to Heme b

[Image: see text] Coproheme decarboxylase (ChdC) catalyzes the last step in the heme biosynthesis pathway of monoderm bacteria with coproheme acting both as redox cofactor and substrate. Hydrogen peroxide mediates the stepwise decarboxylation of propionates 2 and 4 of coproheme. Here we present the...

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Detalhes bibliográficos
Publicado no:ACS Catal
Main Authors: Milazzo, Lisa, Gabler, Thomas, Pühringer, Dominic, Jandova, Zuzana, Maresch, Daniel, Michlits, Hanna, Pfanzagl, Vera, Djinović-Carugo, Kristina, Oostenbrink, Chris, Furtmüller, Paul G., Obinger, Christian, Smulevich, Giulietta, Hofbauer, Stefan
Formato: Artigo
Idioma:Inglês
Publicado em: American Chemical Society 2019
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6691569/
https://ncbi.nlm.nih.gov/pubmed/31423350
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acscatal.9b00963
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