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Crystal structure of a low-spin poly[di-μ(3)-cyanido-di-μ(2)-cyanido-bis­(μ(2)-2-ethyl­pyrazine)­dicopper(I)iron(II)]

In the title metal–organic framework, [Fe(C(6)H(8)N(2))(2){Cu(CN)(2)}(2)](n), the low-spin Fe(II) ion lies at an inversion centre and displays an elongated octa­hedral [FeN(6)] coordination environment. The axial positions are occupied by two symmetry-related bridging 2-ethyl­pyrazine ligands, while...

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Detalhes bibliográficos
Publicado no:Acta Crystallogr E Crystallogr Commun
Main Authors: Partsevska, Sofiia V., Naumova, Dina D., Matushko, Igor P., Kucheriv, Olesia I., Gural’skiy, Il’ya A.
Formato: Artigo
Idioma:Inglês
Publicado em: International Union of Crystallography 2019
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6690451/
https://ncbi.nlm.nih.gov/pubmed/31417793
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1107/S2056989019009496
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