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Active template rotaxane synthesis through the Ni-catalyzed cross-coupling of alkylzinc reagents with redox-active esters
The synthesis of unsymmetrical axle [2]rotaxanes through a recently developed Ni-catalyzed C(sp(3))–C(sp(3)) cross-coupling of redox-active esters (formed directly from carboxylic acids) and organozinc reagents (derived from alkyl bromides) is reported. The method also furnishes, as a minor product,...
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| Publicado no: | Chem Sci |
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| Main Authors: | , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
Royal Society of Chemistry
2019
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6686731/ https://ncbi.nlm.nih.gov/pubmed/31588296 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c9sc02457c |
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