An unusual [4 + 2] fusion strategy to forge meso-N/O-heteroarene-fused (quinoidal) porphyrins with intense near-infrared Q-bands

Here we present a divergent synthesis of brand-new types of meso-N/O-heteroarene-fused (quinoidal) porphyrins through Rh-catalyzed β-C–H activation/annulation of 5,15-dioxoporphyrins and dioxime derivatives with alkynes, in which the synthetic disconnections are difficult to access through the commo...

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Bibliografiske detaljer
Udgivet i:Chem Sci
Main Authors: Li, Chengming, Zhu, Lei, Liang, Wenbo, Su, Rongchuan, Yin, Jiangliang, Hu, Yanmei, Lan, Yu, Wu, Di, You, Jingsong
Format: Artigo
Sprog:Inglês
Udgivet: Royal Society of Chemistry 2019
Fag:
Chemistry
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC6686728/
https://ncbi.nlm.nih.gov/pubmed/31588297
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c9sc01596e
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