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The S∴π hemibond and its competition with the S∴S hemibond in the simplest model system: infrared spectroscopy of the [benzene-(H(2)S)(n)](+) (n = 1–4) radical cation clusters

The S∴π hemibond (two-center three-electron, 2c-3e, bond) is an attractive interaction between a sulfur atom and π electrons. The S∴π hemibond is of essential importance in understanding chemistry of sulfur radical cations, and its roles in biochemistry have recently attracted much interest. In the...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Wang, Dandan, Hattori, Keigo, Fujii, Asuka
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2019
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6685351/
https://ncbi.nlm.nih.gov/pubmed/31588295
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c9sc02476j
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