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Utilizing Carbonyl-Coordination of Native Amides for Pd–catalyzed C(sp(3))–H Olefination
Pd(II)–catalyzed C(sp(3))–H olefination of weakly-coordinating native amides is reported. Three major drawbacks of previous C(sp(3))–H olefination protocols – 1) in situ cyclization of products, 2) incompatibility with α-H-containing substrates, and 3) installation of exogenous directing groups – ar...
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| Publicado no: | Angew Chem Int Ed Engl |
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| Main Authors: | , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2019
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6684442/ https://ncbi.nlm.nih.gov/pubmed/31185132 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201906075 |
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