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Ni-Catalyzed Cross-Electrophile Coupling for the Synthesis of Skipped Polyenes

Skipped polyenes featuring high (E)-selectivity and varying methyl substitution patterns are synthesized using a nickel-catalyzed cross-coupling reaction between allyl trifluoroacetates and vinyl bromides. The utility of this cross-electrophile coupling is showcased in part, by the synthesis of the...

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Detalhes bibliográficos
Publicado no:Org Lett
Main Authors: McGeough, Catherine P., Strom, Alexandra E., Jamison, Timothy F.
Formato: Artigo
Idioma:Inglês
Publicado em: 2019
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6681449/
https://ncbi.nlm.nih.gov/pubmed/31046296
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.9b01019
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