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Generation of Phosphoranyl Radicals via Photoredox Catalysis Enables Voltage−Independent Activation of Strong C−O Bonds

Despite the prevalence of alcohols and carboxylic acids as functional groups in organic molecules and the potential to serve as radical precursors, C−O bonds remain difficult to activate. We report a synthetic strategy for direct access to both alkyl and acyl radicals from these ubiquitous functiona...

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Detaylı Bibliyografya
Yayımlandı:ACS Catal
Asıl Yazarlar: Stache, Erin E., Ertel, Alyssa B., Tomislav, Rovis, Doyle, Abigail G.
Materyal Türü: Artigo
Dil:Inglês
Baskı/Yayın Bilgisi: 2018
Konular:
Online Erişim:https://ncbi.nlm.nih.gov/pmc/articles/PMC6668916/
https://ncbi.nlm.nih.gov/pubmed/31367474
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acscatal.8b03592
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