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Nitrous Oxide-Promoted Pauson-Khand Cycloadditions

A Pauson-Khand cycladdition of alkynes, alkenes, and carbon monoxide, promoted by cobalt carbonyl and nitrous oxide to furnish cyclopentenones is described. Preliminary mechanistic experiments suggest that nitrous oxide functions in a similar manner to the N-oxide promoters typically employed in Pau...

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Bibliografiske detaljer
Udgivet i:Organometallics
Main Authors: Ricker, J. David, Mohammadrezaei, Vahid, Crippen, Thomas J., Zell, Austin M., Geary, Laina M.
Format: Artigo
Sprog:Inglês
Udgivet: 2018
Fag:
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC6667165/
https://ncbi.nlm.nih.gov/pubmed/31363297
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.organomet.8b00810
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