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The cyclopropylcarbinyl route to γ-silyl carbocations
The mesylate derivative of cis-1-hydroxymethyl-2-trimethylsilylcyclopropane has been prepared, along with a number of related mesylates and triflates with substituents on the 1-position. These substrates all solvolyze in CD(3)CO(2)D to give products derived from cyclopropylcarbinyl cations that unde...
Guardat en:
| Publicat a: | Beilstein J Org Chem |
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| Autor principal: | |
| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
Beilstein-Institut
2019
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6664402/ https://ncbi.nlm.nih.gov/pubmed/31435448 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.15.170 |
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