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Potassium chlorido­tris­(hypersil­oxy)aluminate dimer

The tris­(tri­methyl­silylsiloxide) ligand, also known as hypersiloxide, is an extremely bulky group. In an attempt to make the monomeric Al(OSi(SiMe(3))(3))(3), AlCl(3) was combined with 3 equiv. of potassium hypersiloxide. The crystalline product isolated (40% yield), namely di-μ(3)-chlorido-bis­[...

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Detalhes bibliográficos
Publicado no:Acta Crystallogr E Crystallogr Commun
Main Authors: Purdy, Andrew P., Butcher, Raymond J.
Formato: Artigo
Idioma:Inglês
Publicado em: International Union of Crystallography 2019
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6658975/
https://ncbi.nlm.nih.gov/pubmed/31391951
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1107/S2056989019005310
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