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Metal-Free Synthesis of 1,3-Disiloxanediols and Aryl Siloxanols

[Image: see text] The first example of metal-free oxidative hydrolysis of hydrido-siloxanes is reported. Both base-catalyzed and organocatalytic hydrolysis methods are demonstrated to transform 1,3-dihydrido-disiloxanes into 1,3-disiloxanediols. The first example of a chemoselective silane hydrolysi...

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Publicat a:ACS Omega
Autors principals: Kelly, Austin T., Franz, Annaliese K.
Format: Artigo
Idioma:Inglês
Publicat: American Chemical Society 2019
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC6648610/
https://ncbi.nlm.nih.gov/pubmed/31459769
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acsomega.9b00121
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