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Synthesis of Trimetallic (HPd@M(2)Au(8))(3+) Superatoms (M = Ag, Cu) via Hydride-Mediated Regioselective Doping to (Pd@Au(8))(2+)

[Image: see text] We have recently reported that hydride (H(–)) doped superatom (HPd@Au(8))(+) protected by eight PPh(3) ligands selectively grew into (HPd@Au(10))(3+) by the nucleophilic addition of two Au(I)Cl units. In the present study, (HPd@Au(8))(+) was successfully converted to unprecedented...

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Detaylı Bibliyografya
Yayımlandı:ACS Omega
Asıl Yazarlar: Hirai, Haru, Takano, Shinjiro, Tsukuda, Tatsuya
Materyal Türü: Artigo
Dil:Inglês
Baskı/Yayın Bilgisi: American Chemical Society 2019
Online Erişim:https://ncbi.nlm.nih.gov/pmc/articles/PMC6648303/
https://ncbi.nlm.nih.gov/pubmed/31459817
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acsomega.9b00575
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