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Energetics of Saddling versus Ruffling in Metalloporphyrins: Unusual Ruffled Dodecasubstituted Porphyrins

[Image: see text] Presented herein is a first major density functional theory (BP86/D3/STO-TZ2P) survey of the energetics of saddling versus ruffling for a wide range of dodecasubstituted metalloporphyrins with M = Ni, Cu, Zn, Pd, and Pt. For the majority of X(8)TPP (i.e., β-octasubstituted-meso-tet...

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Publié dans:ACS Omega
Auteurs principaux: Conradie, Jeanet, Ghosh, Abhik
Format: Artigo
Langue:Inglês
Publié: American Chemical Society 2017
Accès en ligne:https://ncbi.nlm.nih.gov/pmc/articles/PMC6644939/
https://ncbi.nlm.nih.gov/pubmed/31457262
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acsomega.7b01004
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