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Supramolecular Polymer and Sheet and a Double Cubane Structure in Platinum(IV) Iodide Chemistry: Solution of a Longstanding Puzzle

[Image: see text] The complexes [PtMe(2)(L)], L = 2-C(5)H(4)NCH(2)NH-x-C(6)H(4)OH (x = 2, 3, or 4), react with iodine to form [PtI(2)Me(2)(L)], by trans oxidative addition, when x = 3 or 4, and they are shown to have polymeric or sheet structures formed through NH···I hydrogen bonding. However, liga...

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Veröffentlicht in:ACS Omega
Hauptverfasser: Fard, Mahmood A., Behnia, Ava, Puddephatt, Richard J.
Format: Artigo
Sprache:Inglês
Veröffentlicht: American Chemical Society 2018
Online Zugang:https://ncbi.nlm.nih.gov/pmc/articles/PMC6644743/
https://ncbi.nlm.nih.gov/pubmed/31459156
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acsomega.8b01367
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