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Theoretical Study on the Epimerization of Azlactone Rings: Keto–Enol Tautomerism or Base-Mediated Racemization?
[Image: see text] Azlactones are versatile heterocycles employed in a diversity of transformations; the main drawback of these cycles consists in the epimerization of the α-carbonyl stereocenter during its preparation. We hereby present a theoretical study to explain how the racemization occurs. Two...
Gorde:
| Argitaratua izan da: | ACS Omega |
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| Egile Nagusiak: | , , , |
| Formatua: | Artigo |
| Hizkuntza: | Inglês |
| Argitaratua: |
American Chemical Society
2018
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| Sarrera elektronikoa: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6641619/ https://ncbi.nlm.nih.gov/pubmed/31458601 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acsomega.8b00060 |
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