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Ene Reactions of Nitrosocarbonyl Intermediates with Trisubstituted Cycloalkenes: “Cis Effect” and Steric and Conformational Factors Drive the Selectivity
[Image: see text] Nitrosocarbonyl intermediates, generated at room temperature by oxidation of nitrile oxides, undergo clean ene reactions with trisubstituted cycloalkenes. Nitrosocarbonyl benzene follows a Markovnikov orientation and abstracts preferentially the twix hydrogens over the lone ones. W...
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| Pubblicato in: | ACS Omega |
|---|---|
| Autori principali: | , , , |
| Natura: | Artigo |
| Lingua: | Inglês |
| Pubblicazione: |
American Chemical Society
2018
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| Accesso online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6641422/ https://ncbi.nlm.nih.gov/pubmed/31457923 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acsomega.7b01124 |
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