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Basic Phosphonium Ionic Liquids as Wittig Reagents
[Image: see text] The possibility of designing a solvent/reagent for Wittig reactions from basic phosphonium salts is explored theoretically. In the suggested R(4)P(+)PhO(–) and Ph(3)PR(+)PhO(–) ionic liquids (ILs), the phenolate anion is prone to remove the α-proton from the alkyl chains, forming a...
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| Publié dans: | ACS Omega |
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| Auteurs principaux: | , , |
| Format: | Artigo |
| Langue: | Inglês |
| Publié: |
American Chemical Society
2017
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| Accès en ligne: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6641186/ https://ncbi.nlm.nih.gov/pubmed/31457625 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acsomega.7b00230 |
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