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Sui Generis Helicene-Based Supramolecular Chirogenic System: Enantioselective Sensing, Solvent Control, and Application in Chiral Group Transfer Reaction

[Image: see text] A novel dioxa[6]helicene-based supramolecular chirogenic system (1) as a specific chiral recognition host for enantiopure trans-1,2-cyclohexanediamine (2) is reported. Host 1 with an inherent free phenolic group and a (1S)-camphanate chiral handle on the opposite terminal rings of...

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Publicado en:ACS Omega
Main Authors: Hasan, Mohammed, Khose, Vaibhav N., Mori, Tadashi, Borovkov, Victor, Karnik, Anil V.
Formato: Artigo
Idioma:Inglês
Publicado: American Chemical Society 2017
Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC6641162/
https://ncbi.nlm.nih.gov/pubmed/31457457
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acsomega.6b00522
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