Synthesis and Catalytic Applications of a Triptycene-Based Monophosphine Ligand for Palladium-Mediated Organic Transformations

[Image: see text] 1-Methoxy-8-(diphenylphosphino)triptycene (1), featuring high structural rigidity and steric bulkiness around the phosphine functionality, was synthesized as a new chiral monophosphine ligand for transition metal-catalyzed reactions. In the presence of 5–10 mol ppm (i.e., 0.0005–0....

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Bibliographic Details
Published in:ACS Omega
Main Authors: Leung, Franco King-Chi, Ishiwari, Fumitaka, Shoji, Yoshiaki, Nishikawa, Tsuyoshi, Takeda, Ryohei, Nagata, Yuuya, Suginome, Michinori, Uozumi, Yasuhiro, Yamada, Yoichi M. A., Fukushima, Takanori
Format: Artigo
Language:Inglês
Published: American Chemical Society 2017
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC6640964/
https://ncbi.nlm.nih.gov/pubmed/31457552
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acsomega.7b00200
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